alkyl group

alkyl group (ălˈkĭl) [key], in chemistry, group of carbon and hydrogen atoms derived from an alkane molecule by removing one hydrogen atom (see radical). The name of the alkyl group is derived from the name of its alkane by replacing the - ane suffix with - yl, e.g., methyl, CH3, from methane, CH4, and ethyl, C2H5, from ethane, C2H6. In some cases different alkyl groups can be formed from the same alkane by removing different hydrogen atoms; the alkyl groups are then distinguished by adding a prefix, e.g., 1-propyl or n-propyl, CH2CH2CH3, and 2-propyl or isopropyl, CH(CH3)2, both formed from propane, CH3CH2CH3. When a functional group is joined with an alkyl group, replacing the hydrogen that was removed, a compound is formed whose characteristics depend largely on the functional group.

The Columbia Electronic Encyclopedia, 6th ed. Copyright © 2012, Columbia University Press. All rights reserved.

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